Method of refining nitrogen trifluoride gas

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Halogenous component

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55 71, 55 75, 423406, C01B 719, C01B 21083, B01D 5302

Patent

active

050698877

ABSTRACT:
The invention provides a selective adsorption method for refining NF.sub.3 gas containing CF.sub.4 as impurity. At a temperature not higher than 10.degree. C. the NF.sub.3 gas is brought into contact with a crystalline and porous synthetic zeolite, which is substantially uniform in pore size and about 4.9 .ANG. in effective pore size and is commerciallized under the name of molecular sieve 5A, on condition that the content of water of crystallinity in the synthetic zeolite is 1-10 wt. %, and preferably 6-10 wt. %. The synthetic zeolite efficiently adsorbs NF.sub.3 with little adsorption of CF.sub.4.

REFERENCES:
patent: 4156598 (1979-05-01), Woytek et al.
patent: 4193976 (1980-03-01), Lileck et al.
patent: 4543242 (1985-09-01), Aramaki et al.
patent: 4933158 (1990-06-01), Aritsuka et al.
patent: 4948571 (1990-08-01), Harada et al.

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