Mercaptans by addition of hydrogen sulfide to olefins in presenc

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260609R, 260609E, 260609D, C07C14800, C07C14926, C07C14906

Patent

active

039637859

ABSTRACT:
In a method for preparing mercaptans by the addition of hydrogen sulfide to olefins in the presence of sulfactive catalysts a method is provided for increasing the total conversion of reactants to mercaptans by including carbon disulfide in the reaction mixture. In a preferred embodiment carbon disulfide is present in the reaction mixture of hydrogen sulfide and ethylenically unsaturated compounds in an amount in the molar ratio of about 5/1 to about 30/1 hydrogen sulfide to carbon disulfide.

REFERENCES:
patent: 2402586 (1946-06-01), Alvarado
patent: 3036133 (1962-05-01), Goshorn et al.
patent: 3214386 (1965-10-01), Warner et al.
patent: 3219709 (1965-11-01), Louthan
patent: 3221056 (1965-11-01), Louthan
patent: 3257464 (1966-06-01), Buchholz et al.
patent: 3419614 (1968-12-01), Doss

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