Process for making .alpha.,.beta.-unsaturated carboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562470, C07C 6364

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active

059106069

ABSTRACT:
.alpha., .beta.-Unsaturated acids of the formula ##STR1## wherein R.sup.1 signifies C.sub.1 -C.sub.5 -alkyl and Ar signifies an aryl group which is optionally substituted by one or more substituents selected from the group consisting of halogen, phenyl, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -alkoxy, perfluorinated C.sub.1 -C.sub.5 -alkyl or perfluorinated C.sub.1 -C.sub.5 -alkoxy can be obtained from new or known compounds of the formula ##STR2## Compounds I can be converted by asymmetric hydrogenation into corresponding optically active saturated acids.

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Derwent Abstract No. 89-057709, JP 960 16078, Feb. 21, 1996.
Hayashi, T., et al., J. Am. Chem. Soc., 109:7876-7878 (1987).
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Takemoto, I., et al., Biosci. Biotech. Biochem., 58(11):2071-2072 (1994).
Chemical Abstracts, 53:14939b. (1957).

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