Process for the recovery of gallium and germanium from coal fly

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iva metal

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423133, 423 88, 423542, C01G 1500, C01G 1700

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active

046786473

ABSTRACT:
A method is disclosed for recovering gallium and/or germanium from fly ash which comprises pelletizing the fly ash, treating the pellets in the presence of an oxidizing gas at a temperature of from about 900.degree. C. to just below the fusion temperature of the pellets, treating the pellets in the presence of a reducing gas at the same temperature range, and recovering gallium and/or germanium suboxides from the gas.

REFERENCES:
patent: 4071422 (1978-01-01), Charlton et al.
patent: 4252777 (1981-02-01), McDowell et al.
patent: 4375453 (1983-03-01), Nalewajek et al.
patent: 4475993 (1984-10-01), Blander et al.
Report of Investigation 6940 of the United States Department of the Interior, Bureau of Mines, "Extraction of Germanium and Gallium from Coal Fly Ash and Phosphorous Furnace Flue Dust", by R. F. Waters and H. Kenworthy (1967).

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