Epoxidation of olefins using a titania-supported titanosilicate

Details Epoxidation of olefins using a titania-supported titanosilicate Epoxidation of olefins using a titania-supported titanosilicate

1993-12-23

1994-10-11

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549525, 549529, C07D30112, C07D30114, C07D30119, C07D30304

Patent

active

053548752

ABSTRACT:
The oxidation of olefinic compounds generally using hydroperoxides, especially aqueous solutions of hydrogen peroxide, can be effected in high yield and with good selectivity in the presence of a titania-supported titanosilicate catalyst. Dilute aqueous hydrogen peroxide solutions may be used with good results. The resulting epoxidation, even when carried out at modest temperatures and with dilute aqueous hydrogen peroxide solutions, afford superior results in epoxidation relative to TS-1.

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Notari, B., Innovation in Zeolite Materials Science, Grobet, P. J. et al., Ed.,; Elsevier: Amsterdam, pp. 413-425 (1988)053553921 .

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