Process for the preparation of acetal sulphones

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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260607AR, 260607AL, 260609F, C07C14706

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active

041105389

ABSTRACT:
Acetal sulphones useful as intermediates in the preparation of vitamin A and other terpene compounds are made by reacting a sulphone of the formula: ##STR1## with an .omega.-halogeno-acetal of an ethylenically unsaturated aldehyde of the formula: ##STR2## in which m and n each represent zero or 1 and are such that m+n=1, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be identical or different, represent hydrogen or straight or branched alkyl radical of 1 to 6 carbon atoms, R.sub.6 represents straight or branched alkyl of 1 to 6 carbon atoms, R represents straight or branched alkyl of 1 to 6 carbon atoms or arylalkyl containing a straight or branched alkyl of from 1 to 6 carbon atoms or aryl, unsubstituted or substituted by alkyl, alkoxy, alkylthio, alkoxycarbonyl, hydroxyl or halogen, and R' represents hydrogen or, if m is zero, straight or branched alkyl of 1 to 6 carbon atoms.

REFERENCES:
patent: 3781313 (1973-12-01), Julia
patent: 3803252 (1974-04-01), Chabardes
patent: 3848000 (1974-11-01), Chabardes
patent: 3850991 (1974-11-01), Chabardes
patent: 3865878 (1975-02-01), Chabardes
patent: 3906967 (1976-06-01), Olson

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