Process for manufacturing regenerated cellulose hollow fiber

Plastic and nonmetallic article shaping or treating: processes – Pore forming in situ

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2105002, 2642093, 2642108, 264561, 428398, B29D 2700

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043882560

ABSTRACT:
A regenerated cellulose hollow fiber exhibiting a good cellulose II crystalline structure and an exchanged wet strength/wet elongation ratio is prepared by a process wherein: a dope comprised of cellulose ester in a non-volatile organic solvent is extruded through a circular slit defined between inner and outer tubes of a spinning nozzle having a double tube structure, while a core liquid is forced through the inner tube of said nozzle; the hollow fibrous extrudate is coagulated in a coagulating bath; the coagulated hollow fibrous extrudate is drawn 1.05 to 2.00 times its original length; and then, the drawn hollow fiber still containing a core liquid in the hollow is treated with an aqueous caustic alkali solution containing at least 0.5% by weight of a water soluble metal salt, thereby hydrolyzing the cellulose ester into cellulose.

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patent: 3546209 (1970-12-01), Lipps
patent: 3724672 (1973-04-01), Leonard et al.
patent: 3888771 (1975-06-01), Isuge et al.
patent: 4035459 (1977-07-01), Kesting
patent: 4127625 (1978-11-01), Arisaka et al.
patent: 4219517 (1980-08-01), Kesting
Text Res. J., vol. 19, No. 7, pp. 381-392, 7-1949.

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