Preparation of esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C12000, C07C12166

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active

041103629

ABSTRACT:
Certain carboxylic acid esters also containing a cyano group are prepared by reacting an acid halide, an aldehyde and a water-soluble cyanide in the presence of a water-immiscible aprotic solvent and an onium catalyst.

REFERENCES:
patent: 3835176 (1974-09-01), Matsuo et al.
Zymalkowski et al., Arch. pharmaz Ber. pharmaz. Ges., 62, Nr. 5, pp. 218-224, (1956).
Francis et al., J. Chem. Soc., 95, pp. 1403-1409, (1909).
Kinder et al., Arch. Pharm., 271, pp. 431-439, (1933).
Coronyn, J. Org. Chem., 14, pp. 1013-1022, (1949).
Fisher et al., J. Org. Chem., 24, pp. 1650-1654, (1959).

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