Process for producing unsaturated group-terminated isobutylene p

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526135, 526146, 526147, 526194, 526204, 526209, 526210, 526212, 526217, 526220, 526221, 526222, 526237, 5263487, 525267, 525270, 525288, 525918, 528501, C08F 206, C08F 1010

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058115013

ABSTRACT:
The present invention provides a novel halogen-free solvent system which can produce a good isobutylene polymer and can be easily reused. A novel process for the production of an isobutylene polymer is provided which comprises using a hydrocarbon solvent having a boiling point of not lower than 105.degree. C. and a melting point of not higher than -90.degree. C. Heretofore, a solvent system containing a halogenated hydrocarbon such as methylene chloride has been used for the production of an isobutylene polymer. However, such a solvent system has a great adverse effect on the environment. Therefore, a non-halogenated solvent is desirable. The present invention is characterized by the use of a hydrocarbon solvent as a reaction solvent. The resulting polymer has good properties. Further, compounds which are produced as by-products during the reaction can be easily removed, enabling the recycling of the solvent used. Thus, the production cost can be reduced.

REFERENCES:
patent: 3493549 (1970-02-01), Uemura et al.
patent: 5247021 (1993-09-01), Fujisawa et al.
patent: 5527870 (1996-06-01), Maeda et al.

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