Pure enantiomers of bicyclo[2.2.2]oct-5-en-2-ones, processes for

Details Pure enantiomers of bicyclo[2.2.2]oct-5-en-2-ones, processes for Pure enantiomers of bicyclo[2.2.2]oct-5-en-2-ones, processes for

1981-12-02

1983-11-15

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568361, 568366, 568374, 568591, 568373, 260465D, 560118, 562500, C07C 4500

Patent

active

044157568

ABSTRACT:
New bicyclo[2.2.2]oct-5-en-2-ones of the formulae Ia and Ib in the form of pure enantiomers and processes for preparing them are described. The compounds are used for the preparation of pure enantiomers of the formula V by sensitized photoreaction or of compounds of the formula VI by unsensitized photoreaction.

REFERENCES:
Geivandov et al., Chem. Abst., vol. 95, #24354f, p. 631, (1981).
Torosyan et al., Chem. Abst., vol. 92, #58589q, p. 656, (1980).
Freeman et al., J. Org. Chem., vol. 33, pp. 2211-2214, (1968).
Alforo et al., Tetrahedron, vol. 30, pp. 559, (1974).
Lopatnik et al., Chem. Abst., vol. 95, #115149j, p. 666, (1981).
Monti et al., J. Org. Chem., vol. 43, pp. 4062-4069, (1978).
Mislow et al., J. Am. Chem. Soc., vol. 84, pp. 1956, (1962).

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