Process for recovering oxygenated organic compounds from dilute

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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562606, 562608, 568411, 568492, 568699, 568868, 568869, 568916, C07C 6748, C07C 5142, C07C 4134, C07C 2974

Patent

active

044476434

ABSTRACT:
A thermally efficient process for recovering an oxygenated organic material, such as ethanol, present in dilute aqueous solution is disclosed which comprises contacting said dilute aqueous solution with at least one inert extractant which is liquid at ambient temperature and pressure, said extractant being selected from the group consisting of unsubstituted and substituted cyclic secondary amines and unsubstituted and substituted aromatic cyclic amines having a distribution coefficient of at least about 0.70 or a separation factor of at least about 1.0. The invention further provides a process for obtaining substantially anhydrous oxygenated organic material from a dilute aqueous solution thereof in which the stream is subjected to liquid-liquid extraction to provide an oxygenated organic material poor raffinate phase and an oxygenated organic material rich extract phase, the oxygenated organic material present in said latter phase is concentrated in a rectifying column to provide an aqueous oxygenated organic material of high concentration and, if desired or necessary, the concentrated stream is azeotropically distilled in an anhydrous column operated under substantially superatmospheric pressure with thermal values recovered from said anhydrous column being used to satisfy part of all of the thermal operating requirements of the rectifying column.

REFERENCES:
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patent: 2691669 (1954-10-01), Walker
patent: 2791550 (1957-05-01), West et al.
patent: 3904676 (1975-09-01), Curtis
patent: 3980701 (1976-09-01), Grinstead
patent: 4032583 (1977-06-01), Arganbright et al.
patent: 4143066 (1979-03-01), Kalcevic

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