Two-stage process for preparing aromatic polyamide fiber

Plastic and nonmetallic article shaping or treating: processes – Formation of solid particulate material directly from molten... – By extrusion spraying or gravity fall through orifice

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264 13, 264141, 264561, 264180, 264181, 264184, 2642103, 2642104, 2642106, 2642108, 26421116, D01D 526, D01F 660

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048760404

ABSTRACT:
A process for preparing aromatic polyamide fibers wherein an aromatic diamine and an aromatic diacidchloride are dissolved in an amide polymerization solvent containing an inorganic salt, a partial polymerization is effected at a low temperature to form an optically anisotropic liquid crystalline prepolymer dope, and the liquid crystalline prepolymer dope is subjected to a molecular orientating polymerization in a polymerization accelerating-precipitation solvent to provide aromatic polyamide fibers free of a crystal defect layer perpendicular to the fiber axis and having high strength and high degree of molecular orientation.

REFERENCES:
patent: 4511623 (1985-04-01), Yoon et al.
Journal of Polymer Science: Polymer Physics Edition, vol. 21, 1955-1969 (1983).
Journal of Polymer Science: Polymer Physics Edition, vol. 21, 1957-1983 (1983).

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