Electrochemical oxidation of alkyl aromatic compounds

Chemistry: electrical and wave energy – Processes and products

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C25B 302

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044591861

ABSTRACT:
Aromatic ketones may be prepared by subjecting an alkyl aromatic compound containing more than one carbon atom in the alkyl substituent to an electrical energy which includes a direct electrical current in the presence of a nucleophile such as an organometallic oxide, a solvent and a reaction initiator such as an alkali metal hydroxide and a quaternary ammonium hydroxide to produce a ketal, following which the ketal may be converted to the desired ketone by hydrolysis.

REFERENCES:
patent: 4148696 (1979-04-01), Halter

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