Method of spinning a nylon yarn having improved retention of a s

Plastic and nonmetallic article shaping or treating: processes – With printing or coating of workpiece

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264176F, 528336, B29C 5900, C08J 936, C08G 6904, D01F 690

Patent

active

045914737

ABSTRACT:
This invention is a method to improve retention of a finish on nylon yarn, said finish containing the reaction product of epichlorohydrin with the reaction product of pyromellitic dianhydride with a long chain fluoroalcohol, comprising polymerizing said nylon in the presence of about 0.5 to 1 mole percent of a primary-tertiary diamine of the structure ##STR1## where R.sub.1 is an alpha, omega-alkylene group of 2 to 10 carbon atoms where cycloaliphatic, R.sub.2 and R.sub.3 are alkyl radicals of 1 to 4 carbon atoms, R.sub.4 is an alkylene radical of 1 to 10 carbon atoms and R.sub.5 is R.sub.4 or arylalkyl, R.sub.6 is H or alkyl of 1 to 4 carbons, so that said nylon polymer is melt stable. Also, for batch processing, polyethyleneimines of 300 to 1200 molecular weight, methylaminobispropylamine, N-(2-aminoethyl)-1,3-propanediamine, and 3,3'-iminobispropylamine are useful.

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