Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal
Patent
1980-12-09
1983-05-17
Carter, Herbert T.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Group vib metal
423DIG14, 4236585, 75101BE, 210684, C01G 3900, C01G 4100
Patent
active
043839800
ABSTRACT:
The instant invention relates to a process for removing tungsten, and/or molybdenum generally, as the tungstate and/or the molybdate anion, from aqueous solutions, e.g. brines by contacting such solutions with a high-surface area oxide selected from the group consisting of manganese and iron oxides, preferably manganese or iron hydrous oxide, whereby tungsten or molybdenum is adsorbed on said high-surface area oxide. The instant process provides selectivity for tungsten as well as molybdenum even though they are present in solutions containing various other materials such as sodium, potassium, calcium, etc. ions. This process is preferably applicable to removal of tungsten from high pH brines such as a brine having a pH of at least 9, for example greater than 10. The oxide adsorbent may be regenerated by contacting with an aqueous solution having a pH higher than the brine from which the tungsten and/or the molybdenum has been removed.
REFERENCES:
patent: 3332737 (1967-07-01), Kraus
patent: 3804945 (1974-04-01), Scott et al.
Meloni et al., "Chemical Absts.", vol. 70, 1969, #120757u.
Amphlett, "Inorganic Ion Exchangers", Elseuier Pub. Co., N.Y., 1964, pp. 84-88, 113.
Moulik et al., Jour. Indians Chem. Soc.", vol. 47, 1970, pp. 149-153.
Baran Robert J.
Carter Herbert T.
Occidental Research Corporation
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