Process for alkylene oxide polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

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C08G 6512

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046670130

ABSTRACT:
The molecular weight of polyalkylene oxides produced by the polymerization of a cyclic oxide in contact with a catalyst comprising the reaction product of a dihydrocarbyl zinc compound and a linear alkanediol in contact with a silica dispersion aid and nonionic surfactant in an inert diluent is controlled by the continuous addition of a very dilute solution of chain transfer agent having a pKa value of from 9 to 22 to the polymerizing mixture during the polymerization reaction at a carefully controlled rate so as not to terminate the polymerization reaction.

REFERENCES:
patent: 3382192 (1968-05-01), Kawamura et al.
patent: 3385800 (1968-05-01), Furukawa et al.
patent: 3639267 (1972-02-01), Vandenberg
Shoichi Asano, et al., J. Chem. Soc., Chem. Commun. 1985, 1148-9.
Bruce and Rabigliati, Polymer (London), 8, 361-367 (1966).

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