Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...
Patent
1986-05-02
1987-05-19
Nielsen, Earl
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From heterocyclic reactant containing as ring atoms oxygen,...
C08G 6512
Patent
active
046670130
ABSTRACT:
The molecular weight of polyalkylene oxides produced by the polymerization of a cyclic oxide in contact with a catalyst comprising the reaction product of a dihydrocarbyl zinc compound and a linear alkanediol in contact with a silica dispersion aid and nonionic surfactant in an inert diluent is controlled by the continuous addition of a very dilute solution of chain transfer agent having a pKa value of from 9 to 22 to the polymerizing mixture during the polymerization reaction at a carefully controlled rate so as not to terminate the polymerization reaction.
REFERENCES:
patent: 3382192 (1968-05-01), Kawamura et al.
patent: 3385800 (1968-05-01), Furukawa et al.
patent: 3639267 (1972-02-01), Vandenberg
Shoichi Asano, et al., J. Chem. Soc., Chem. Commun. 1985, 1148-9.
Bruce and Rabigliati, Polymer (London), 8, 361-367 (1966).
Gibson Henry H.
Nielsen Earl
Union Carbide Corporation
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