Optically active alcohols and process for producing the same

Details Optically active alcohols and process for producing the same Optically active alcohols and process for producing the same

1989-11-17

1991-01-22

Hollrah, Glennon H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549209, 549215, 549513, 549523, 549550, 556 12, 556 87, 568715, 568812, 568822, 568838, 568839, 568841, 568842, 568843, C07D30304, C07D30308, C07F 708, C07F 722

Patent

active

049872362

ABSTRACT:
Provided herein is an optically active alcohol having a silyl group, stannyl group, or halogen atom at the .gamma.-position, selected from compounds represented by the general formula [I], ##STR1## the general formula [II], ##STR2## the general formula [III], ##STR3## and the general formula [IV], ##STR4## (where, R denotes a C.sub.1 -C.sub.10 substituted or unsubstituted alkyl group or substituted or unsubstituted phenyl group; A denotes a silyl group represented by ##STR5## a stannyl group represented by ##STR6## or a halogen atom, R.sup.1, R.sup.2, and R.sup.3 are substituted or unsubstituted C.sub.1 -C.sub.10 alkyl groups or substituted or unsubstituted phenyl group, which may be the same or different, provided that this does not apply in the case where A represents a stannyl group or halogen atom in the general formulas [III] and [IV].); a process for producing the same, and a process for resolving the optically active alcohol into isomers of high optical purity.

REFERENCES:
Bulletin of the Chemical Society of Japan, vol. 52(9), pp. 2646-2652 (1979), M. Obayashi et al.
Tetrahedron Letters, vol. 23, No. 52, pp. 5579-5582, 1982, Pergamon Press Ltd., A. S. Narula.
Tetrahedron Letters, vol. 24, No. 48, pp. 5421-5424, 1983, Pergamon Press Ltd., Oxford, GB, A. Narula.
Chemical Communications, Journal of the Chemical Society, No. 17, Sep. 1, 1986, pp. 1323-1325, Y. Kitano et al.
Tetrahedron Letters, vol. 28, No. 18, pp. 2033-2036, 1987, Pergamon Journals Ltd., Oxford, GB; S. Okamoto et al.
Tetrahedron Letters, vol. 28, No. 18, pp. 2041-2044, 1987, Pergamon Journals Ltd., GB; A. T. Russell et al.

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