Preparation of 4 and 5-methylindanes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260566R, 260668R, C07C 4752

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039681637

ABSTRACT:
Indane is reacted with an .alpha.,.alpha.-dichloromethyl lower alkyl ether, the reaction mixture is treated with water to produce a mixture of 4-formylindane and 5-formylindane, the aldehyde isomers are separated and the aldehydes are catalytically hydrogenated to produce 4-methylindane and 5-methylindane.

REFERENCES:
wagner, et al., Synthetic Organic Chem., John Wiley & Sons Inc., pp. 284-285 & 728-729 (1965).
Olah, Friedel Crafts & Related Reactions, Interscience Publishers, pp. 118-119 (1963).

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