Coated optical fibers having a reduced content of extractable an

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522 44, 522 79, 522 90, 522 96, 385123, 385128, 385145, 428378, 428392, C08J 704, G02B 602

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active

057445141

ABSTRACT:
Coated optical fibers with radiation-curable coatings which include mercaptofunctional oligomers are disclosed. Specifically, the coatings may comprise the cured reaction products of mercapto-terminated urethane oligomers of number average molecular weight as determined by gel permeation chromatography (GPC) of at least about 3,000 daltons, particularly in combination with one or more (meth)acrylate-terminated urethane oligomers; monomer diluents; and optional silane adhesion promoter, photoinitiator and stabilizers. The coatings, when cured, exhibit a percent extractables content, as obtained by Soxhlet extraction, of no more than about 15%, and preferably of no more than about 8%, and a volatiles content, as obtained by thermogravimetric analysis, of less than about 7%, and preferably less than about 3%. Processes for preparing such coated optical fibers and the coatings per se are also disclosed.

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