Process for the production of phosphoric acid and calcium fluori

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

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4231573, 423490, C01B 2522, C01F 1122

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active

055319750

ABSTRACT:
Fluosilicic acid is reacted with phosphate rock in order to produce wet process phosphoric acid and calcium fluoride which is later reacted with sulfuric acid to produce hydrogen fluoride and calcium sulfate. The hydrogen fluoride is then stripped from the phosphoric acid and recovered as either anhydrous hydrogen fluoride or concentrated hydrofluoric acid or reacted with aluminum trihydrate to produce aluminum fluoride; with sodium carbonate to produce sodium fluoride/bifluoride; or with ammonia to produce ammonium fluoride/bifluoride.

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U.S. Dept. of Interior Report of Investigations 8061, Fluosilicic Acid Acidulation of Phosphate Rock, by L. H. Banning, Albany Metallurgy Research Center, Albany, Oregon (1975).
Chemical Abstracts, vol. 84, No. 18, 3 May 1976 (Columbus, Ohio US) H. Lloyd Banning: "Fluosilicic Acid Acidulation of Phosphate Rock," p. 127 abstract No. 123995v, and U.S., Bur. Mines, Rep. Invest. 1975, RI 8061, 13 pages.
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Chemical Abstracts 78(8):519775.

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