Novel aminocyclitols and process for production thereof

Details Novel aminocyclitols and process for production thereof Novel aminocyclitols and process for production thereof

1976-08-30

1978-06-06

Brown, Johnnie R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

424180, 536 4, C07H 1522

Patent

active

040937976

ABSTRACT:
Novel .beta.-D-ribofuranosyl (1 .fwdarw. 5), O-[.alpha.-D-2-amino(or 2-acylamino)-2, 3-dideoxy-glucopyranosyl (1 .fwdarw. 4) ] 1, 3-diamino (or 1, 3-diacylamino)-1, 2, 3-trideoxy-myoinositols and their acid salts. These compounds are useful either as antibiotics or as intermediates for their synthesis. The compound can be produced by treating an O-.alpha.-L-2, 6-diacylamino-2, 6-dideoxyidopyranosyl (1 .fwdarw. 3), .beta.-D-ribofuranosyl (1 .fwdarw. 5), O-[.alpha.-D-2-acylamino-2, 3-dideoxy-glucopyranosyl (1 .fwdarw. 4)] 1, 3-diacylamino-1, 2, 3-trideoxy-myoinositol with periodic acid or its salts, reacting the resulting compound with an amine, and optionally deacylating the product.

REFERENCES:
patent: 3872080 (1975-03-01), Daniels
patent: 3878193 (1975-04-01), Reimann
patent: 3928317 (1975-12-01), Kirby et al.
patent: 3960833 (1976-06-01), Naito et al.

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