Preparation of unsaturated aliphatic insect pheromones using cyc

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260395, 542412, 556405, 556482, 556436, 560234, 560240, 568 12, 568 15, 568626, 568442, C07D30906, C07C 4118, C07F 704

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042960428

ABSTRACT:
This process relates to the synthesis of unsaturated aliphatic esters useful as insect sex attractants, including gossyplure, the insect sex pheromone of the pink bollworm moth, Pectinophora gossypiella, and intermediates therefor. The process utilizes a cyclic phosphonium (Wittig) reagent.

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patent: 3996270 (1976-12-01), Friedman et al.
Henrick, Tetrahedron, vol. 33, pp. 1845-1889 (1977).
Johnson, "Ylid Chemistry", Academic Press, Inc., New York (1966) pp. 23-32, 125-131.
Sonnet, J. Org. Chem., 39, 3793(1974).
Hummel et al., Science, 181, 873 (1973).

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