Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-12-04
1977-01-25
Gotts, Lewis
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260 47XA, C07C 6806
Patent
active
040051218
ABSTRACT:
A process for the preparation of linear aliphatic polycarbonates having terminal hydroxyl groups is carried out in two stages:
I. in the first stage, the transesterification is carried out in the presence of a basic catalyst at a temperature below 140.degree. C, and
Ii. in the second stage, after complete destruction of the basic catalyst, the transesterification is completed in the presence of an acid catalyst at a temperature of between 200.degree. and 250.degree. C.
The polycarbonate-diols obtained are useful for the preparation of polyurethane elastomers which are resistant to hydrolysis.
REFERENCES:
patent: 2915529 (1959-12-01), Bell
patent: 3549682 (1970-12-01), Vernaleken et al.
Gotts Lewis
Phillips D. R.
Societe Nationale des Poudres et Explosifs
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