Electrolysis of halide-containing solutions with platinum based

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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148403, 204 98, 204293, C25B 124

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active

045604541

ABSTRACT:
A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode having the formula

REFERENCES:
patent: 3856513 (1974-12-01), Chen et al.
patent: 4036638 (1977-07-01), Ray et al.
patent: 4339270 (1982-07-01), Hashimoto et al.
Electrochimica Acta, pp. 1215-1220, "The Anodic Polarization Behavior of Amorphous Pd-T-P Alloys in NaCl Solutions", Hara, Hashimoto & Masumoto.
Journal of Applied Electrochemistry 13, pp. 295-306, "Anodic Characteristics of Amorphous Ternary Palladium-Phosphorus Alloys Containing Ruthenium, Rhodium, Iridium or Platinum in a Hot Concentrated Sodium Chloride Solution", Hara, Hashimoto & Masumoto.
Journal of Non-Crystalline Solids 54, pp. 85-100, "Anodic Characteristics of Amorphous Palladium-Iridium-Phosphorus Alloys in a Hot Concentrated Sodium Chloride Solution, Hara, Hashimoto & Masumoto.

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