Process for synthesis of a novel amino acid from styrene, acetam

Details Process for synthesis of a novel amino acid from styrene, acetam Process for synthesis of a novel amino acid from styrene, acetam

1988-07-14

1992-03-17

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

C07C22936

Patent

active

050970658

ABSTRACT:
A phenyl substituted amino acid derivative is synthesized by reacting styrene, acetamide and synthesis gas with a bimetallic catalyst comprising a rhodium-containing compound and a cobalt-containing compound, optionally in the presence of a solvent at a pressure of at least 500 psi and a temperature of at least 50.degree. C. The novel amino acid contains a carboxylic acid group, an acetamido group at the alpha-position and a phenyl group at the beta-position.

REFERENCES:
patent: 3766266 (1973-10-01), Wakamatsu et al.
patent: 4675439 (1987-06-01), Mita et al.
Tou et al., J. Org. Chem., vol. 49, pp. 1135-1136 (1984).
Falbe, "Carbon Monoxide in Organic Synthesis", pp. 3-45 (1970).

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