Production method of an insect pheromone

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D31102

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045117268

ABSTRACT:
A process for producing 3,3,7-trimethyl-2,9-dioxatricyclo[3.3.1.0.sup.4,7 ]nonane useful as an insect pheromone and having the formula, ##STR1## which comprises reducing 1,5,5-trimethyl-7-endo-tert-butyldimethylsilyloxy-4-oxabicyclo[4.2.0]octan -3-one with diisobutylaluminum hydride, and treating with an acid, after desilylation.

REFERENCES:
patent: 4296036 (1981-10-01), Mori et al.
Journal of Chemical Ecology, vol. 3, No. 5, pp. 549-561 (1977).
The Canadian Entomologist, vol. 112, pp. 107-109 (1980).
Tetrahedron, vol. 36, pp. 2197-2208 (1980).
Journal of the Organic Chemistry, vol. 45, pp. 2290-2297 (1980).

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