Method for producing singlet molecular oxygen

Details Method for producing singlet molecular oxygen Method for producing singlet molecular oxygen

1977-08-12

1978-07-25

Meros, Edward J.

Chemistry of inorganic compounds

Oxygen or compound thereof

252372, C01B 1302

Patent

active

041029500

ABSTRACT:
A method and generator are provided for producing singlet molecular oxygen, O.sub.2 (.sup.1 .DELTA..sub.g). A hypohalite selected from the group consisting of BrSO.sub.3 F, BrNO.sub.3, BrOCF.sub.3, ClSO.sub.3 F, ClNO.sub.3, Cl0CF.sub.3, FSO.sub.3 F, FOCF.sub.3, and ISO.sub.3 F, is reacted with hydrogen peroxide to produce singlet molecular oxygen. A preferred embodiment of the reaction is illustrated by the following example:

REFERENCES:
patent: 3780165 (1973-12-01), Schack et al.
patent: 3980762 (1976-09-01), Shiblom et al.
Braver "Handbook of Preparative Inorganic Chemistry", vol. 1, 1963, pp. 158 & 159.
Cotton et al., "Advanced Inorganic Chemistry", Third Ed., 1972, pp. 411 & 412.
Kearns, "Chemical Reviews," 1971, vol. 71, No. 4, pp. 395-411.
Foote et al., "J. Am. Chem. Soc., 90, 1968, pp. 975-981.

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