Olefin polymerization method

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526124, 526128, 526351, 502116, C08F 444

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active

051823411

ABSTRACT:
A method of polymerizing one or more 1-olefins using a catalyst system incorporating a solid catalyst component is disclosed wherein the catalyst component is prepared by contacting, in the presence of an inert liquid hydrocarbon, silica, a soluble organomagnesium compound, an SiCl.sub.4 magnesium fixing agent, an alcohol, TiCl.sub.4, and a carboxylic acid derivative, followed by extraction with a TiCl.sub.4 containing extraction liquid. The inventive catalyst system allows ready control of product molecular weight by control of hydrogen concentration in the reactor, and allows the production of high MI or MF polymers at high productivities.

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