Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1991-07-29
1995-03-07
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
C07F 708, C07F 718
Patent
active
053959558
ABSTRACT:
This invention provides method for the preparation of carbinol-modified organopolysiloxane which does not suffer from the secondary reaction problems of the art and which thereby makes possible the production of high-purity carbinol-containing organopolysiloxane.
The method involves a platinum-catalyzed addition reaction of an organopolysiloxane having at least 1 silicon-bonded hydrogen atom in each molecule and an organic compound whose molecule contains at least 1 aliphatically unsaturated hydrocarbon group and at least 1 triorganosilyl-blocked carbinol group. Thereafter a desilylation reaction on the organopolysiloxane product is accomplished in an essentially water-free mixture of organic carboxylic acid and alcohol to provide carbinol-modified organopolysiloxane.
REFERENCES:
patent: 2629727 (1953-02-01), Speier
patent: 2924588 (1960-02-01), Speier
patent: 3442925 (1969-05-01), Sinuler et al.
patent: 4375548 (1983-03-01), Wang et al.
patent: 5113005 (1992-05-01), Celebriski
Mikami Ryuzo
Okawa Tadashi
Dow Corning Toray Silicone Company, Ltd.
Grindahl George A.
Shaver Paul F.
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