Novel solid polymer electrolytes

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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252 622, H01M 1040

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active

050615815

ABSTRACT:
An amorphous ionically conductive macromolecular solid is set forth having improved ambient temperature ionic conductivity. The solid comprises a solid solution of at least one positively charged ionic species dissolved in a macromolecular material, the macromolecular material comprising a polymer or copolymer having a polyether structure and having at least a portion of the ether oxygens thereof replaced with S or NR wherein R includes at least one basic site capable of associating with the positively charged ionic species and has 2 to 10 carbon atoms. Relatively high conductivity is a feature of the macromolecular solid of the invention.

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patent: 4683181 (1987-07-01), Armand et al.
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M. B. Armand, "Current State of PEO-Based Electrolyte", in Polymer Electrolyte Reviews, Eds. MacCallum and Vincent.
P. M. Blonsky et al., J. Am. Chem Soc. 106:6854 (1984).
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D. F. Shriver et al., "Solid Ionic Conductors", in Chemical & Engineering News, May 20, 1985.
P. V. Wright, Br. Polymer J. 7:319 (1975).

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