Process for forming a bromomagnesium tetrakis (fluorophenyl) bor

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From boron reactant having at least one boron to hydrogen or...

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568 6, C08G 7908

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054730368

ABSTRACT:
Bromomagnesium tetrakis(fluorophenyl) borate reactible intermediates can be formed by reacting at least four equivalents of fluorophenyl magnesium bromide with every one equivalent of boron trifluoride in ether solvent using a sufficient amount of heat to drive the reaction to completion. This type of reactible intermediate can then be reacted with a salt containing a suitable cation, such as ammonium, trityl or onium, preferably substituted with phenyl or alkyl, such as lower alkyl, to form the desired combination of weakly coordinating boron anion and activating cation.

REFERENCES:
patent: 4894302 (1990-01-01), Hoffman et al.
patent: 5296433 (1994-03-01), Siedle et al.
patent: 5340898 (1994-08-01), Cavezzan et al.
patent: 5362423 (1994-11-01), Ikeda et al.
patent: 5399780 (1995-03-01), Ikeda et al.
patent: 5420355 (1995-05-01), Ikeda et al.
A. G. Massey et al, "Perfluorophenyl Derivatives of the Elements: I. Tris(Pentafluorophenyl)Boron", Journal of Organometallic Chemisty, 2 (1964), 245-250.
J. L. W. Pohlmann et al., "Pentafluorophenyl-Metal Chemistry II: Preparation and Characterization of Group IIIA Derivatives", Z. Naturforschg. 20b, 5-11 (1965).
Japanese Patent Abstracts, vol. 13 No. 39(C-563), abstracting Japanese Patent Publication No. 63-238087 (Oct. 1988) entitled "Novel Tetraaryl Borate", Applicant: Central Glass Co. Ltd.; Inventor: H. Kobayashi.
M. Brookhart et al., "[(3,5-(CF.sub.3).sub.2 C.sub.6 H.sub.3).sub.4 B].sup.- [H(OEt.sub.2).sub.2 ].sup.+ : A Convenient Reagent for Generation and Stabilization of Cationic, Highly Electrophilic Organometallic Complexes", Organometallics 1992, 11, 3920-3922.
H. Nishida et al., "Tetrakis[3,5-Bis(Trifuoromethyl)Phenyl]Borate. Highly Lipophilic Stable Anionic Agent for Solvent-Extraction of Cations", Bull. Chem. Soc. Jpn. 57, 2600-2604 (1984).
Abstract in English) of International Patent Publication No. WO 94/00459 (Jan.1994) and copy of International Search Report.
Chemical Abstracts, vol. 112 (1990), 77273e.
J. C. W. Chien et al., "Isospecific Polymerization of Propylene Catalyzed by rac-Ethylenebis(indenyl)methylzirconium `Cation`", J. Am. Chem. Soc. 113, 8570-8571 (1991).

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