Continuous process for biocatalytic desulfurization of sulfur-be

Chemistry: molecular biology and microbiology – Process of utilizing an enzyme or micro-organism to destroy... – Petroleum oil or shale oil treating

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435281, 210601, 210624, 208237, C10G 3200, C10G 2920, C02F 300, C02F 302

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054728754

ABSTRACT:
A continuous cyclic process for desulfurizing a petroleum liquid which contains organic sulfur molecules, a significant portion of which are comprised of sulfur-bearing heterocycles. This process involves oxygenating the petroleum liquid and treating it with a biocatalyst capable of catalyzing the sulfur-specific oxidative cleavage of organic carbon-sulfur bonds in sulfur-bearing aromatic heterocyclic molecules such as dibenzothiophene. a particularly preferred biocatalyst is a culture of mutant Rhodococcous rhodocrous bacteria, ATCC No. 53968. In the present process, the activity of this biocatalyst is regenerated; it can be used for many cycles of treatment. A system for conducting the continuous cyclic process of biocatalytic desulfurization of petroleum liquids is also disclosed.

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