Preparation of amino terminated polyacrylics

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253304, 5253306, 525369, 526208, 526211, 526328, C08F 812

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054929776

ABSTRACT:
Amino terminated polyacrylic acids and polyacrylic acrylates are prepared by free radical polymerization of the acid or acrylate monomers with t-Boc-aminoethanethiol as a chain transfer control agent followed by acid removal of the t-Boc group. The acids and their acrylates are precursors to form dispersants and to modify dyes.

REFERENCES:
1993 article in the Journal Macromolecules, vol. 26, No. 9, pp. 2240-2245 by Shefer, Grodzinsky, Prime and Busnel entitled "Free-Radical Telmerization of tert-Butyl Acrylate in the Presence of Bis(4-aminophenyl) Disulfide as a Useful Route to Amino-Terminated Telomers of Poly(acrylic acid)".

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