Process for preparing polyacrylonitrile filaments having high te

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – Shaping by extrusion

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264206, 2642106, 2642108, 264203, 264211, 26421116, D01F 618

Patent

active

049138707

ABSTRACT:
Polyacrylonitrile articles, such as filaments, tapes and films, having high tensile strength and modulus, and prepared by adding to a solution of polyacrilonitrile with a molecular weight above 3.times.10.sup.5, preferably above 5.times.10.sup.5, a minor amount of a bivalent metal compound, converting the solution into a solvent containing article, cooling this article to form a gel article, removing from this gel the solvent and metal compound, and stretching the resulting article at increased temperature. With this process filaments with a tensile strength above 1.2 GPa and a modulus above 16 GPa can be obtained.

REFERENCES:
patent: 4173606 (1979-11-01), Stoy et al.
patent: 4352852 (1982-10-01), DeMaria

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