Process of preparing a durable electrode by plasma spraying an i

Coating processes – Spray coating utilizing flame or plasma heat – Metal oxide containing coating

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4271263, 4271266, 4273763, 4273764, 427380, C23C 410, B05D 512

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054927323

ABSTRACT:
Provided is a process for producing a durable low hydrogen over-voltage cathode. An interim coating is applied to a metallic substrate by plasma spraying an intermetallic compound comprising at least 10% cerium oxide by x-ray diffraction analysis and at least one non-noble Group 8 metal. The metallic substrate bearing the interim coating is then heated in a non-oxidizing atmosphere including an inert gas to produce the electrode.

REFERENCES:
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patent: 5021304 (1989-03-01), Ruka et al.
patent: 5314601 (1994-05-01), Hardee et al.
Hall et al, Hydrogen Evolution Cathodes With AB.sub.5 -Catalyzed Coatings, Inco Alloys International, Inc., pp. 184-194.
Hall, Plasma-sprayed nickel cathode coatings for hydrogen evolution in alkaline electrolytes, Journal of Applied Electrochemistry, vol. 14, 1984, pp. 107-115.
Semenenko et al, Electrochemical Properties of Intermetallic Hydride-Polymeric Binder Composite Electrodes, Plenum Publishing Corporation, 1984, pp. 525-527.
Patent Abstracts of Japan, re: JP-A-54-090-080. Dec. 1977.
Patent Abstracts of Japan, re: JP-A-51-117-181 Oct. 1976.

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