Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Halogen or compound containing same
Patent
1993-10-01
1994-10-25
McFarlane, Anthony
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Halogen or compound containing same
502224, 502226, 502229, 502231, B01J 27122
Patent
active
053589190
ABSTRACT:
Novel compositions, being effective as catalysts for alkane and/or cycloalkane isomerization, are prepared by a method which includes the steps of impregnating alumina with a sulfate of at least one metal selected from the group consisting of copper, iron, cobalt, nickel, manganese, zinc and magnesium, calcining the thus-obtained impregnated alumina materials, and heating the calcined materials with AlCl.sub.3 and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at a temperature of about 40.degree.-90.degree. C. Preferably, this method also includes a step of treating the calcined impregnated alumina materials with gaseous hydrogen chloride before the heating with AlCl.sub.3 and the chlorinated hydrocarbon(s) is carried out.
REFERENCES:
patent: 2820074 (1958-01-01), Pines
patent: 2963528 (1960-12-01), Schwartz
patent: 3238272 (1966-03-01), Nixon
patent: 3248343 (1966-04-01), Kelly et al.
patent: 3420909 (1969-01-01), Schmerling
patent: 3502735 (1970-03-01), Copelin
patent: 3523072 (1970-08-01), Schneider
patent: 3631211 (1971-12-01), Schmerling
patent: 3655797 (1972-04-01), Schmerling
patent: 3846503 (1974-11-01), Schmerling et al.
patent: 5004859 (1991-04-01), Schmidt et al.
patent: 5202519 (1993-04-01), Khare
patent: 5219817 (1993-06-01), McDaniel et al.
patent: 5221655 (1993-06-01), McDaniel et al.
patent: 5238896 (1993-08-01), Khare
patent: 5254794 (1993-10-01), Wu
patent: 5292988 (1994-03-01), Wu
N. Kitajima, "Two Component Friedel-Crafts Catalysts as Solid Superacids", Materials Chemistry and Physics 17 (1987), pp. 31-48.
N. Kitajima et al., "Cu(AlCl.sub.4).sub.2 as a Catalyst for the Isomerization of Pentane at Room Temperature", Journal of Molecular Catalysis 10 (1981), pp. 121-122.
Y. Ono et al., "Isomerization of Pentane with AlCl.sub.3 -CuSo.sub.4 Mixtures", Journal of Catalysis 64 (1980), pp. 13-17.
N. Kitajima et al., "On the Active Species of Aluminum(III) Bromide-Copper(II) Bromide Mixtures as Catalysts for the Isomerization of Pentane", Journal Chem. Society, Perkin Transactions II, 1980, pp. 1201-1205.
Y. Ono et al., "Isomerization of Pentane with Aluminum Chloride (Gallium Chloride)-Cupric Salt Complexes", Proceedings 7th Internat. Congress Catalys., Tokyo, 1980, pp. 1006-1017.
Y. Ono et al., "Highly Selective Isomerization of Pentane with AlBr.sub.3 -Metal Sulfate Mixtures", Chemistry Letters, 1978, pp. 1061-1064.
Brandes K. K.
McFarlane Anthony
Phillips Petroleum Company
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