Preparation and use of isomerization catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Halogen or compound containing same

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502224, 502226, 502229, 502231, B01J 27122

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active

053589190

ABSTRACT:
Novel compositions, being effective as catalysts for alkane and/or cycloalkane isomerization, are prepared by a method which includes the steps of impregnating alumina with a sulfate of at least one metal selected from the group consisting of copper, iron, cobalt, nickel, manganese, zinc and magnesium, calcining the thus-obtained impregnated alumina materials, and heating the calcined materials with AlCl.sub.3 and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at a temperature of about 40.degree.-90.degree. C. Preferably, this method also includes a step of treating the calcined impregnated alumina materials with gaseous hydrogen chloride before the heating with AlCl.sub.3 and the chlorinated hydrocarbon(s) is carried out.

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