Separation of 1,1,1-trichloroethane from the lower alcohols by e

Distillation: processes – separatory – Adding material to distilland except water or steam per se – Organic compound

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Other Related Categories

203 58, 203 60, 203 62, 203 63, 203 64, 568913, 570262, B01D 340, C07C 1738, C07C 2984

Type

Patent

Status

active

Patent number

051960940

Description

ABSTRACT:
1,1,1-Trichloroethane cannot be completely separated from methanol, ethanol, n-propanol, isopropanol, 2-butanol or t-butanol by conventional distillation or rectification because of the minimum boiling azeotropes. 1,1,1-Trichloroethane can be readily separated from these alcohols by extractive distillation. A typical effective agent is dimethylsulfoxide.

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patent: 3658657 (1972-04-01), Bursack et al.
patent: 3989601 (1976-11-01), Boozalis et al.
patent: 4220609 (1980-09-01), McEntee et al.
patent: 5106460 (1992-04-01), Berg
patent: 5118392 (1992-06-01), Berg
patent: 5131985 (1992-07-01), Berg et al.

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