Two stage hydrotreating pretreatment in production of olefins fr

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Plural serial stages of chemical conversion

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208 61, 208143, 208 97, C10G 6508, C10G 6906

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active

046197575

ABSTRACT:
Low-molecular weight olefins from heavy hydrocarbons are obtained with a hydrogenating pretreatment and a subsequent thermal cracking of at least a portion of the hydrogenated product. In the first stage, the polyaromatic content of a first hydrocarbon fraction high in polyaromatic compounds, e.g., a vacuum gas oil, is selectively degraded with a zeolitic hydrotreating catalyst, and in a second stage the resultant hydrocarbons are refined with a non-zeolitic hydrotreating catalyst in admixture with a second heavy hydrocarbon fraction low in polyaromatic compounds, e.g., and atmospheric gas oil. This two-stage process permits the utilization of lower operating pressures as compared to the separate treatment of the heavy hydrocarbon fractions.

REFERENCES:
patent: 3161586 (1964-12-01), Watkins
patent: 3898299 (1975-08-01), Jones
patent: 3944481 (1976-03-01), Wing et al.
patent: 4019976 (1977-04-01), Cosyns et al.
patent: 4145276 (1979-03-01), Cosyns et al.
patent: 4188281 (1980-02-01), Wernicke et al.
patent: 4324935 (1982-04-01), Wernicke et al.

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