Selected phosphorus complexes of zerovalent iron

Details Selected phosphorus complexes of zerovalent iron Selected phosphorus complexes of zerovalent iron

1975-10-15

1976-12-14

Demers, Arthur P.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431P, 2604653, C07F 1502

Patent

active

039975797

ABSTRACT:
Selected novel phosphorus complexes of zerovalent iron containing phosphite ester ligands and, optionally diphosphine ligands, e.g., pentakis(trimethyl phosphite iron) and bis[ethylenebis(diphenylphosphine)] (trimethyl phosphite) iron, are disclosed. The compounds are prepared by various methods, by cocondensation of the vapors of iron and the ligand compound on a cold surface, e.g.,

REFERENCES:
patent: 3450732 (1969-06-01), Wilke et al.
patent: 3903120 (1975-09-01), Shook et al.
Malatesta et al. Ferovalent Compounds of Metals; Academic Press N.Y.; NY, 1904 p. 202-205.
Muerterties et al. J.C.S. Chem Comm. 1974 p. 850-851.
Meakin et al. J. Am. Chem. Soc. 97 (1975) p. 1254-1255.

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