Conjoint production of ditertiary butyl peroxide and tertiary bu

Details Conjoint production of ditertiary butyl peroxide and tertiary bu Conjoint production of ditertiary butyl peroxide and tertiary bu

1993-11-12

1994-09-06

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568558, 568840, C07C 29132, C07C 3112

Patent

active

053450094

ABSTRACT:
A method for conjointly preparing tertiary butyl alcohol and ditertiary butyl peroxide wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium supported on pelleted carbon, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.

REFERENCES:
patent: 2854487 (1958-09-01), Quin
patent: 3474151 (1969-10-01), Grane
patent: 4294999 (1981-10-01), Grame et al.
patent: 4551553 (1985-11-01), Tayler et al.
patent: 4705903 (1987-11-01), Sanderson et al.
patent: 4810809 (1989-03-01), Sanderson et al.
patent: 4900850 (1990-02-01), Sanderson et al.
patent: 5025113 (1991-06-01), Sanderson et al.

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