Graft copolymers of alkyl methacrylates onto cross-linked butadi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 63, 525 66, 525 67, 525 80, 525 81, 525 82, 525 83, 525 85, 525293, 525296, 525302, 525305, 525309, 525310, C08L 3904, C08L 5100

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045672342

ABSTRACT:
The impact resistance of resin compositions consisting of a thermoplastic polymer, particularly a homopolymer or copolymer of vinyl chloride, can be improved by an impact additive of the graft copolymer type. The graft copolymer impact additive consists of a backbone composed of a statistical copolymer of butadiene or isoprene, an alkyl acrylate of a C.sub.2 to C.sub.12 alkyl, and a polyfunctional cross-linking agent, onto which are grafted the chains of a polymer of an alkyl methacrylate of a C.sub.1 to C.sub.4 alkyl, particularly methyl methacrylate. The backbone of the graft copolymer impact additive comprises 0.5-35% by weight butadiene or isoprene, and up to 10 mole % of the cross-linking agent, while the weight ratio of grafted chains to the backbone can range from 10 to 200%.
The resin compositions are particularly useful to improve impact strength at low temperatures.

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