Selective hydrogenation of nitro groups on nitroaromatic acetyle

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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260571, 260575, 260580, 260578, C07C 7922, C07C 8511, C07C 8524

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042196795

ABSTRACT:
Aromatic nitroacetylene compounds wherein both the nitro and acetylene groups are directly connected to aromatic ring carbon atoms are hydrogenated at high conversion levels to selectively reduce the nitro function using an unsupported cobalt polysulfide catalyst. Of particular interest is the preparation of aminophenylacetylenes from nitrophenylacetylene.

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