Metal recovery from porous materials

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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252626, 423251, 20415743, B01F 100

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active

051548992

ABSTRACT:
A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

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Nadkarni, R. A., "Applications of Microwave Oven Sample Dissolution in Analysis", Anal. Chem., 1984 pp. 2233-2237.

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