Process for preparing tertiary phosphines

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

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568 8, C07F 950

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active

045075018

ABSTRACT:
A tertiary phosphine oxide, such as triphenylphosphine oxide, is reduced to the corresponding tertiary phosphine in the presence of a sodium aluminum hydride/aluminum chloride reducing agent.

REFERENCES:
patent: 3261871 (1966-07-01), Fritzsche et al.
patent: 3280195 (1966-10-01), Fritzsche et al.
patent: 3847999 (1974-11-01), Gardner et al.
patent: 4008282 (1977-02-01), Townsend et al.
patent: 4113783 (1978-09-01), Malpass et al.
patent: 4131624 (1978-12-01), Davis et al.
Chemical Abstracts 53 9879c (1959).
Chemical Abstracts 61 8335f (1964).
Chemical Abstracts 63 8398h (1966).
Kosolapoff et al., Organic Phosphorus Compounds, Wiley-Intersc. Pub. N.Y., vol. 1, pp. 45-47 (1972).

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