Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1985-08-30
1986-10-21
Garvin, Patrick P.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
5263485, 526352, 502113, C08F 464
Patent
active
046186603
ABSTRACT:
An olefin polymerization catalyst produced by treating an inert support material, preferably a hydrated high surface area silica support having 1.00 to 1.50 hydroxyls per gram of silica with the reaction product of an organomagnesium compound and first a zirconium compound then a halogenator and tetravalent titanium compound, which when used as a cocatalyst with an organoaluminum compound produces polymers having broad molecular weight distribution.
REFERENCES:
patent: 3678025 (1972-07-01), Birrell
patent: 4109071 (1978-08-01), Berger et al.
patent: 4210559 (1980-07-01), Melquist et al.
patent: 4471066 (1984-09-01), Sakurai et al.
Exxon Research & Engineering Co.
Garvin Patrick P.
Kurtzman M. B.
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