Process for preparing unsaturated alcohols

Details Process for preparing unsaturated alcohols Process for preparing unsaturated alcohols

1975-11-10

1977-06-07

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260680R, C07C 2900

Patent

active

040284247

ABSTRACT:
Unsaturated alcohols are prepared by reacting an .alpha.-olefin such as isobutene with an aldehyde such as formaldehyde in the presence of a phosphate preferably in an organic solvent. Unsaturated alcohols such as 3-methyl-3-butene-1-ol and 3-methyl-2-butene-1-ol are important intermediates for producing organic compounds such as isoprene.

REFERENCES:
patent: 3544603 (1970-12-01), Morrisroe et al.
Naito, et al., Chem. Absts., 80, 84457(s), 1974.
Kumano, et al., Chem. Absts., 81, 13082(a), 1974.
Kituchi, et al. Chem. Absts., 81, 79095(p), 79096(q), 79097(r), 1974.
Oriendale, et al., Chem. Rev., 51, 506-511, 1952.
Chlebicki, Chem. Abst., 77, 138952(h), (1972).
Chlebicki, Chem. Abst., 78, 111519(f), (1973).
W. Barendrecht, Chem. Abst., vol. 54, 5426(a), (1960).

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