Fluorine containing polymer having a terminal ester group

Details Fluorine containing polymer having a terminal ester group Fluorine containing polymer having a terminal ester group

1988-06-29

1989-08-15

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526250, 526254, 526255, C08F 1220

Patent

active

048576190

ABSTRACT:
A fluorine containing polymer having a terminal ester group is prepared from the free radical polymerization of an acyclic ketane acetal with a vinyl monomer component including a fluorine containing vinyl monomer.
The fluorine containing polymer can be utilized to prepare functional oligomers suitable for many uses including film former and additives for coating applications.

REFERENCES:
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patent: 3480603 (1969-11-01), Selman et al.
patent: 3502732 (1970-03-01), Selman et al.
Bailey et al., "Free Radical Ring-Opening Polymerization and Its Use to Make Biodegradable Polymers and Functionally Terminated Oligomers", Makromol. Chem., Symp. 6, 81, (1986).
"Preparation of Poly(Ortho Esters) by the Reaction of Diketene Acetals and Polyols", Journal of Polymer Science: Polymer Letters Edition, vol. 18, 619-624, (1980), copyright 1980 by John Wiley & Sons, Inc.
Dunn and Plesch, "The Cationic Polymerization of Ketene Acetals and the Preparation and Characterization of Poly(1,3-Diketones)", Die Makromolekulare Chemie, 175, 2821-2836, (1974).
Bailey et al., "Synthesis of Poly-e-Caprolactone Via a Free Radical Mechanism, Free Radical Ring-Opening Polymerization of 2-Methylene-1,3-Dioxepane", Journal of Polymer Science: Polymer Chemistry Edition, vol. 20, 3021-3030, (1982), copyright 1982 by John Wiley & Sons, Inc.
"Photoinitiated Ring-Opening Polymerization of 2-Methylene-1,3-Dioxepane", Journal of Polymer Science: Polymer Letters Edition, vol. 21, 373-380, (1983), copyright 1983 by John Wiley & Sons, Inc.
Endo, Fukada, Hirota, "Reaction of Cyclic Ketene Acetal and Carbon Disulfide Through Macrozwitterion", Journal of the American Chemical Society, 1984, 106, 4035-4036.
Bailey et al., "Synthesis of Functionally-Terminated Oligomers by Free Radical Ring-Opening Polymerization", J. Macromol. Sci. Chem. Azi (8 & 9), 979-995, (1984) copyright 1984 by Marcel Dekker, Inc.
Bailey et al., "Free Radical Ring-Opening Polymerization of 4,7-Dimethyl-2-Methylene-1,3-Dioxepane and 5,6-Benzo-2-Methylene-1,3-Dioxepane", Macromolecules, 15, 711, (1982).
Bailey, Gapud, "Synthesis of Biodegradable Polyethylene", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 58, (1984).
Bailey et al., "The Use of Free Radical Ring-Opening Polymerization for the Synthesis of Reactive Oligomers", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 142, (1984).
Bailey, "Free Radical Ring-Opening Polymerization", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 210, (1984).

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