Titanocenes and a radiation-polymerizable composition containing

Details Titanocenes and a radiation-polymerizable composition containing Titanocenes and a radiation-polymerizable composition containing

1985-12-11

1987-12-15

Bleutge, John C.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Compositions to be polymerized by wave energy wherein said...

522 66, 430286, 430925, 430947, 526170, 556 53, C08F 250, C08F 476, C08L 3314

Patent

active

047134011

ABSTRACT:
Titanocenes with .pi.-cyclopentadienyl ligands, in which one or two carbocyclic or heterocyclic aromatic rings are bonded to the metal, the aromatic rings being substituted in at least one of the two ortho-positions relative to the metal-carbon bonds by CF.sub.2 Z (Z=F or substituted or unsubstituted alkyl), are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds. They are distinguished by a high radiation sensitivity, stability to air and thermal effects, and high effectiveness in the range from UV light to visible light.

REFERENCES:
patent: 4530879 (1985-07-01), Drahnak
patent: 4548891 (1985-10-01), Riediker et al.
patent: 4590287 (1986-05-01), Riediker

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