LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeabl

Chemistry: electrical current producing apparatus – product – and – Having earth feature

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429 27, 429 59, 429101, 429218, 420900, H01M 486

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058886656

ABSTRACT:
An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

REFERENCES:
patent: 4121924 (1978-10-01), de Barbadillo, II
patent: 4142300 (1979-03-01), Gruen et al.
patent: 4147536 (1979-04-01), Osumi et al.
patent: 4378331 (1983-03-01), Bruning et al.
patent: 4409180 (1983-10-01), Sandrock et al.
patent: 5085944 (1992-02-01), Ebato et al.
patent: 5306583 (1994-04-01), Bouet et al.
patent: 5434022 (1995-07-01), Anani et al.
A. Hightower et al., "Performance of LaNi.sub.4.7 Sn.sub.0.3 Metal Hydride Electrodes in Sealed Cells", Long Beach Battery Conference, 1998.
C. Witham, et al., "Electrochemical Properties of LaNi.sub.5-x Ge.sub.x Alloys in Ni-MH Batteries", J. Electrochem. Soc., vol. 144, No. 11, Nov. 1997.
A.R. Miedema; The Heat of Formation of Alloys, Philips Technical Review, vol. 36, 1976, No. 8; pp. 217-231. (month N/A).
A.R. Miedema, et al.; Model Predictions for the Enthalpy of Formation of Transition Metal Alloys; CALPHAD, vol. 1, No. 4, pp. 341-359, Pergamon Press, 1977; Printed in Great Britain. month N/A.
M.H. Mendelsohn, et al.; The Effect on Hydrogen Decomposition Pressures of Group IIIA and IVA Element Substitutions for Ni in LaNi.sub.5 Alloys, Materials Research Bulletin, vol. 13, pp. 1221-1224, Sep. 25, 1978. Pergamon Press, Inc.; Printed in the United States.
M. Mendelsohn, et al.; Group 3A and 4A Substituted AB.sub.5 Hydrides; Inorganic Chemistry, vol. 18, No. 12, pp. 3343-3345; Mar. 5, 1979.
A.R. Miedema, et al.; Cohesion in Alloys-Fundamentals of a Semi-Empirical Model; Physica 100B (1980) pp. 1-28; North-Holland Publishing Company; Dec. 7, 1979.
A.K. Niessen, et al.; Model Predictions for the Enthalpy of Formation of Transition Metal Alloys II; CALPHAD, vol. 7, No. 1, pp. 51-70; 1983 (month N/A).
F. W. Oliver, et al.; Mossbauer Studies on LaNi.sub.4.7 Sn.sub.0.3 and its Hydride; J. Appl. Phys., 57(1); Apr. 15, 1985.
J.J.G. Willems, et al.; From Permanent Magnets to Rechargeable Hydride Electrodes; Journal of the Less-Common Metals, 129 (1987) pp. 13-30. (month N/A).
Tetsuo Sakai, et al.; The Influence of Small Amounts of Added Elements on Various Anode Performance Characteristics for LaNi.sub.2.5 CO.sub.2.5 -Based Alloys; Journal of the Less-Common Metals, 159 (1990) pp. 127-139. (month N/A).
Tetsuo Sakai, et al.; Some Factors Affecting the Cycle Lives of LaNi.sub.5 -Based Alloy Electrodes of Hydrogen Batteries; Journal of the Less-Common Metals, 161(1990) pp. 193-202 (Month N/A).
R. Balasubramaniam, et al.; Solution Thermodynamics of Hydrogen in the Mischmetal-Ni.sub.5 System with Aluminum Manganese and Tin Substitutions; Journal of Alloys and Compounds, 185 (1992) pp. 259-271. (month N/A).
R. Balasubramaniam, et al.; Hydriding Properties of MmNi.sub.5 System with Aluminum, Manganese and Tin Substitutions; Journal of Alloys and Compounds, 196 (1993); pp. 63-70 (month N/A).
Dhanesh Chandra, et al.; Cyclic Stability of Rare Earth Pentanickel Hydrides; Rare Earths, Extraction, Preparation and Applications; The Minerals, Metals & Materials Society, 1988. (month N/A).
I. Matsumoto and A. Ohta Matshushita; Metal Hydride Batteries and MpH Alloys; presented at the IBA Conference, Seattle, Washington; Oct. 1990.
Konstantin Petrov, et al.; Optimization of Composition and Structure of Metal-Hydride Electrodes; Journal of the Electrochemical Society, vol. 141, No. 7, pp. 1747-1750; Jul., 1994.
Anaba A. Anani, et al.; Mechanically-Alloyed Hydrogen Storage Materials with High Gas Phase and Electrochemical Storage Capacities; Spring Meeting, Honolulu, Hawaii, May 16-21, 1993; The Electrochemical Society, Inc., Extended Abstracts, vol. 93-1, pp. 82-83, Abstract No. 55.
Konstantin Petrov, et al.; Optimization of Composition and Structure of Metal-Hydride Electrodes; Spring Meeting, Honolulu, Hawaii; May 16-21, 1993; The Electrochemical Society, Extended Abstracts, vol. 93-1, pp. 41-42, Abstract No. 27.
A. Anani, et al.; Characterization of an Sn-Modified AB.sub.5 -Type Alloy for Hydrogen Storage and Battery Applications; Fall Meeting, Toronto, Canada; Oct. 11-16, 1992; The Electrochemical Society, Inc., Extended Abstracts, vol. 92-2, p. 99, Abstract No. 64.
Konstantin Petrov, et al.; Sn-Modified AB.sub.5 Type Alloys Prepared by Mechanical Alloying and Arc-melting Methods, for Hydride Electrodes; Fall Meeting, New Orleans, Louisiana, Oct. 10-15, 1993; The Electrochemical Society, Inc., vol. 93-2, Extended Abstracts, pp. 78-79, Abstract No. 46.
T. Sakai, et al.; Nickel-Metal Hydride Batteries, Using Rare-Earth Based Hydrogen Storage Alloys; Proceedings of the Symposium on Hydrogen Storage Materials, Batteries and Electrochemistry; The Electrochemical Society, Proceedings vol. 92-5, pp. 59-91, 1992. (month N/A).
J. McBreen, et al.; In Situ XAS Studies of Metal Hydride Electrodes; Spring Meeting, San Francisco, California, May 22-27, 1994, The Electrochemical Society, Inc., Extended Abstracts, vol. 94-1, p. 1198, Abstract No. 773.
M.P. Sridhar Kumar, et al.; Effect of Ce, Co and Sn Substitution on Gas-Phase and Electrochemical Hydriding/Dehydriding Properties of LaNi5; Spring Meeting, San Francisco, California, May 22-27, 1994, The Electrochemical Society, Inc., Extended Abstracts, vol. 94-1, pp. 1225-1226, Abstract No. 790.
A. Anani, et al.; Hydrogen Storage In Modified AB.sub.5 -type Alloys for Battery and Fuel Cell Applications; Fall Meeting, Toronto, Ontario, Canada, Oct. 11-16, 1992, The Electrochemical Society, Inc., Extended Abstracts, vol. 92-2, p. 720, Abstract No. 489.
C.K. Witham, et al.; Microstructural Effects of Hydrogen Charging and Discharging on LaNi.sub.5-x Sn.sub.x ; Fall Meeting, Miami Beach, Florida, Oct. 9-14, 1994, The Electrochemical Society, Inc., Extended Abstracts, vol. 94-2, pp. 58-59, Abstract No. 38.
Konstantin Petrov, et al.; Optimization of Structure and Composition Metal-Hydride Electrodes, Using Sn-Modified AB.sub.5 Type Alloy; Fall Meeting, New Orleans, Louisiana, Oct. 10-15, 1993; The Electrochemical Society, Extended Abstracts, vol. 93-2, pp. 80-81, Abstract No. 47.
B.V. Ratnakumar, et al.; Studies on AB.sub.5 Metal Hydride Alloys with Sn Additives; Fall Meeting, Miami Beach, Florida, Oct. 9-14, 1994, The Electrochemical Society, Extended Abstracts, vol. 94-2, pp. 56-57, Abstract No. 37.
M. Tadokoro, et al.; Development of Hydrogen Absorbing Alloys for Nickel Metal Hydride Secondary Batteries; The Electrochemical Society, Proceedings of the Symposium on Hydrogen Storage Materials, Batteries, and Electrochemistry, vol. 92-5; pp. 92-104, 1992 (month N/A).
B. V. Ratnakumar, et al.; Studies on AB.sub.5 Metal Hydride Alloys with Sn Additives; Proceedings of The Symposium on Hydrogen and Metal Hydride Batteries; Fall Meeting, Miami Beach Florida, Oct. 9-14, 1994, The Electrochemical Society, Inc., Battery Division, Proceedings vol. 94-27, pp. 57-67.
C.K. Witham, et al., Microstructural Effects of Hydrogen Charging and Discharging on LaNi.sub.4.8 Sn.sub.0.2, Proceedings of the Symposium on Hydrogen and Metal Hydride Batteries; Fall Meeting, Miami Beach, Florida, Oct. 9-14, 1994, The Electrochemical Society, Inc., Battery Division, Proceedings vol. 94-27, p. 68-77.
B. V. Ratnakumar, et al.; Electrochemical Studies on LaNi.sub.5-x Sn.sub.x Metal Hydride Alloys; J. Electrochem. Soc. vol. 143, No. 8, Aug. 1996, pp. 2578-2583.
C. Witham, et al.; Electrochemical Evaluation of Lani5-x Gex Metal Hydride Alloys; J. Electrochem. Soc. vol. 143, No. 9, Sep. 1996, L-205-L208.

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