Electrochemical production of higher pentafluorosulfonyl acid fl

Chemistry: electrical and wave energy – Processes and products

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204 59R, C25B 308

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active

052863522

ABSTRACT:
A continuous process for preparing in a Simons electrochemical cell charged with anhydrous liquid HF and a S- and H-containing organic precursor fluorochemical compounds having the formula F.sub.5 S--R.sub.f --X where X is COF or SO.sub.2 F; R.sub.f is a saturated fluoroaliphatic radical having at least 3 fully-fluorinated C atoms; and the F.sub.5 S group is bonded via a S--C bond to 1 of the 3 fully-fluorinated C atoms of the R.sub.f radical.

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